Naphthalene-1,8-dicarb­oxy­lic anhydride: a monoclinic polymorph

نویسندگان

  • Dan Zhao
  • FeiFei Li
  • AiYun Zhang
چکیده

A new type of naphthalene-1,8-dicarb-oxy-lic anhydride, C(12)H(6)O(3), was synthesized hydro-thermally. Unlike the two previously reported polymorphs, which crystallize in the ortho-rhom-bic space groups P2(1)2(1)2(1) [Shok et al. (1971). Kristallografiya, 16, 500-502; Grigor'eva & Chetkina (1975). Kristallografiya, 20, 1289-1290] and Pbca [Shok & Gol'der (1970). Zh. Strukt. Khim.11, 939-940], this present structure crystallizes in the monoclinic space group P2(1)/c. In this structure, the planar [total puckering amplitude Q = 0.0362 (15)] mol-ecules lie parallel to each other along the a axis.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

4,5-Dicarb­oxy­naphthalene-1,8-dicarb­oxy­lic anhydride–1,10-phenanthroline (1/1)

In the crystal structure of the title 1:1 adduct, C(12)H(8)N(2)·C(14)H(6)O(7), the carboxyl groups are involved in inter-molecular O-H⋯O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers. These dimers are further linked by inter-molecular O-H⋯N hydrogen bonds. C-H⋯O inter-actions also occur between the 1,10-phenanthroline (phen) and 4,5-dicarb-oxy-naphthalene-1,8-dicarb-oxy-...

متن کامل

4-[(E)-2-Ferrocenylethen­yl]-1,8-naphthalic anhydride

In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system. In the crystal structure, centrosymmetric dimers are formed through π-π inter-actions [centroid-centroid distance = 3.624 (2) Å] between the substituted ferrocene ring and the three fused r...

متن کامل

Naphthalene-1,4,5,8-tetra­carboxylic acid 1,8-anhydride–4,4′-bipyridine (1/1)

The title compound, C(14)H(6)O(7)·C(10)H(8)N(2), has been hydro-thermally synthesized. Structural ananlysis indicates that the crystals are produced by cocrystallization of naphthalene-1,4,5,8-tetra-carboxylic acid 1,8-anhydride and 4,4'-bipyridine (bpy) mol-ecules. The crystal packing is stabilized by inter-molecular O-H⋯N and C-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centr...

متن کامل

A second monoclinic polymorph for 3-amino-1-(4-meth­oxy­phen­yl)-9,10-dihydro­phenanthrene-2,4-dicarbonitrile

The title compound, C(23)H(17)N(3)O, has been previously described in a monoclinic P2(1)/c polymorph with Z = 4 [Asiri, Al-Youbi, Faidallah, Ng & Tiekink (2011). Acta Cryst. E67, o2449]. In the new monoclinic P2(1)/n form, with Z = 8, there are two independent mol-ecules, A and B, in the asymmetric unit. In both mol-ecules, the cyclo-hexa-1,3-diene ring has a screw-boat conformation, whereas it...

متن کامل

Synthesis and X-ray Crystal Structure of Meso-5,5,7,12,12,14- hexamethyl-1,4,8,11-tetraazacyclotetradecane-1,8-di-(1-methyl- naphthalene)

The pendant-arm macrocycle, meso-5,5,7,12,12,14-hexamethyl-1,4,8,11tetraazacyclotetradecane-1,8-di-(1-methylnaphthalene) has been synthesized and its single crystal structure determined. The molecule crystallizes in a primitive monoclinic cell, with the space group P21/a (#14). The cell dimensions are a = 10.778(3)Å, b = 13.809(3) Å, c = 11.420(2) Å, ∃ = 102.49(2)°, volume = 1659.5(6) Å.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010